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Physical Properties
Chapter Name : Haloalkanes And Haloarenes
Sub Topic Code : 102_12_10_05_01
Topic Name : Physical Properties
Sub Topic Name : Physical Properties
Introduction

• Alkyl halides are colourless when pure. However, bromides and iodides develop colour when exposed to light. • Many volatile halogen compounds have sweet smell • Methyl chloride, methyl bromide, ethyl chloride and some chlorofluoromethanes are gases at room temperature. • Higher members are liquids or solids. • Molecules of organic halogen compounds are generally polar. • The attractions get stronger as the molecules get bigger in size and have more electrons. • Bromo, iodo and polychloro derivatives of hydrocarbons are heavier than water. • The density increases with increase in number of carbon atoms, halogen atoms and atomic mass of the halogen atoms. • The haloalkanes are only very slightly soluble in water.

Pre-Requisites:

Elements, bond, halides

Activity:

• Synthetic halogen compounds, viz. • Chloroquine is used for the treatment of malaria. • Halothane is used as an anaesthetic during surgery.

Real Life Question:

What are haloarenes and haloalkanes?

Key Words / FlashCards
Key Words Definitions (pref. in our own words)
- Haloalkanes - Haloarenes • Haloalkanes contain halogen atom(s) attached to the sp3 hybridised carbon atom of an alkyl group. • Haloarenes contain halogen atom(s) attached to sp2 hybridised carbon atom(s) of an aryl group.
Learning aids / Gadgets
Gadgets How it can be used
Chlorine • Chlorine containing antibiotic, chloramphenicol, produced by soil microorganisms is very effective for the treatment of typhoid fever.
Real life uses :

• Synthetic halogen compounds, viz. ? chloroquine is used for the treatment of malaria; ? Halothane is used as an anesthetic during surgery..

Places to visit :

Pharmacy.

Practical examples around us
Examples Explainations
• Synthetic halogen compounds, viz. ? chloroquine is used for the treatment of malaria; ? Halothane is used as an anesthetic during surgery. • Synthetic halogen compounds, viz. ? chloroquine is used for the treatment of malaria; ? Halothane is used as an anesthetic during surgery.
What you learn in Theory:

• Alkyl halides are colourless when pure. However, bromides and iodides develop colour when exposed to light. • Many volatile halogen compounds have sweet smell • Methyl chloride, methyl bromide, ethyl chloride and some chlorofluoromethanes are gases at room temperature. • Higher members are liquids or solids. • Molecules of organic halogen compounds are generally polar. • The attractions get stronger as the molecules get bigger in size and have more electrons. • Bromo, iodo and polychloro derivatives of hydrocarbons are heavier than water. • The density increases with increase in number of carbon atoms, halogen atoms and atomic mass of the halogen atoms. • The haloalkanes are only very slightly soluble in water.

What you learn in Practice:

• Haloalkanes and Haloarenes are classified based on the number of halogen compounds contained in them.

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