Chemical Bonding And Molecular Structure | Limitations Of Octet Rule lesson Plan and Notes :: Danielitte

Chemistry ( 102-11 )

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Some Basic Concepts Of Chemistry

Importance Of Chemistry

Importance Of Chemistry
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Nature Of Matter

Nature Of Matter
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Properties Of Matter And Their Measurement

The International System Of Units (Si)
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Mass And Weight
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Uncertainty In Measurement

Scientific Notation
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Significant Figures
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Dimensional Analysis
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Laws Of Chemical Combinations

Law Of Confirmation Of Mass
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Law Of Definite Proportions
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Law Of Multiple Proportions
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Gay Lussac's Law Of Gaseous Volumes
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Avogadro's Law
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Dalton's Atomic Theory

Dalton's Atomic Theory
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Atomic And Molecular Masses

Atomic Mass
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Average Atomic Mass
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Molecular Mass
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Formula Mass
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Mole Concept And Molecular Mass

Mole Concept And Molecular Mass
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Percentage Composition

Percentage Composition
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Empirical Formula For Molecular Formula
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Stoichiometry And Stoichiometric Calculations

Stoichiometry And Stoichiometric Calculations
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Limiting Reagent
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Reactions In Solutions
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Structure Of Atom

Sub-Atomic Particles

Discovery Of Electron
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Charge To Mass Ratio Of An Electron
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Charge On The Electron
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Discovery Of Protons And Neutrons
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Atomic Models

Thomson's Model Of An Atom
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Rutherford's Nuclear Model Of Atom
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Atomic Number And Mass Number
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Isobars And Isotopes
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Drawbacks Of Rutherford's Model
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Developments Leading To The Bohr's Model Of Atom

Wave Nature Of Electro Magnetic Radiation
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Particle Nature Of Electro Magnetic Radiation: Plank's Quantum Theory
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Evidence For The Quantized Electronic Levels: Atomic Spectra
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Bohr's Model For Hydrogen Atom

Bohr's Model For Hydrogen Atom
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Explanation Of Line Spectrum Of Hydrogen
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Limitations Of Bohr's Model
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Towards Quantum Mechanical Model Of An Atom

Dual Behavior Of Matter
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Heisenberg's Uncertainty Principle
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Quantum Mechanical Model Of Atom

Quantum Mechanical Model Of Atom
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Orbitals And Quantum Numbers
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Shapes Of Atomic Orbitals
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Energies Of Orbitals
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Filling Of Orbitals In An Atom
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Electronic Configuration Of Atoms
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Stability Of Completely Filled And Half Filled Atomic Orbitals
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Classification Of Elements And Periodicity In Properties

Needs Of Classification Of Elements

Needs Of Classification Of Elements
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Genesis Of Periodic Classification

Genesis Of Periodic Classification
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Modern Periodic Law And The Present Form Of Periodic Table

Modern Periodic Law And The Present Form Of Periodic Table
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Nomenclature Of Elements With Atomic Numbers >100

Nomenclature Of Elements With Atomic Numbers >100
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Electronic Configurations Of Elements And Periodic Table

Electronic Configurations Of Elements And Periodic Table
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Electronic Configurations And Types Of Elements S- , P- , D- , F- Blocks

The S- Block Elements
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The P- Block Elements
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The D- Block Elements (Transition Elements)
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The F- Block Elements (Inner Transition Elements)
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Metals , Non-Metals And Metalloids
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Periodic Trends In Properties Of Elements

Atomic Radius
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Ionic Radius
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Ionization Enthalpy
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Electron Gain Enthalpy
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Electronegativity
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Periodicity Of Valence Or Oxidation States
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Anomalous Properties Of Second Period Elements
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Periodic Trends In Chemical Reactivity
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Chemical Bonding And Molecular Structure

Introduction

Introduction
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Kossel-Lewis Approach To Chemical Bonding

Kossel - Lewis Approach to Chemical Bonding
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Octet rule
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Covalent Bond
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Lewis Representation Of Simple Molecules (the Lewis Structures)
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Formal Charge
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Limitations of Octet Rules
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Covalent Bond
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Ionic Or Electrovalent Bond

Ionic Or Electrovalent Bond
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Lattice Enthalpy
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Lewis Representation Of Simple Molecules
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Bond Parameters

Bond Length
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Bond Angle
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Bond Enthalpy
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Bond Order
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Resonance Structures
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Polarity Of Bond
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Formal Charge
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The Valence Shell Electron Pair Repulsion Theory

Vesper Theory
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Limitations Of Octet Rule
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Valence Bond Theory

Valence Bond Theory
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Orbital Overlap Concept
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Directional Properties Of Bonds
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Overlapping Of Atomic Orbitals
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Types Of Overlapping And Nature Of Covalent Bonds
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Strength Of Sigma And Pi Bonds
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Hybridization

Hybridization
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Types Of Hybridization
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Other Examples Of Hybridization
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Hybridization Of Elements Involving D Orbitals
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Molecular Orbital Theory

Molecular Orbital Theory
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Linear Combination Of Atomic Orbitals
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Conditions For The Combination Of Atomic Orbitals
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Types Of Molecular Orbitals
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Energy Level Diagram For Molecular Orbitals
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Electronic Configuration And Molecular Behavior
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Bonding In Some Homonuclear Diatomic Molecules

Bonding In Some Homonuclear Diatomic Molecules
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Hydrogen Bonding

Cause Of Formation Of Hydrogen Bond
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Types Of H- Bonds
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States Of Matter

Introduction

Introduction
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Intermolecular Forces

Intermolecular Forces
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Dispersion Forces And London Forces
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Dipole - Dipole Forces
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Dipole Induced Dipole Forces
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Hydrogen Bond
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Thermal Energy

Thermal Energy
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Intermolecular Forces V/S Thermal Interactions

Intermolecular Forces V/S Thermal Interactions
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The Gaseous State

The Gaseous State
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The Gas Laws

Boyle's Law Pressure Volume Relationship
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Charle's Law (Temperature-Volume Relationship)
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Gay Lussac's Law ( Pressure Temperature Relationship)
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Avogadro's Law (Volume - Amount Relationship)
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Ideal Gas Equation

Density And Molar Mass Of A Gaseous Substance
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Dalton's Law Of Partial Pressures
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Kinetic Molecular Theory Of Gases

Kinetic Molecular Thyeory Of Gases
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Behavior Of Real Gases: Deviation From Real Gas Behavior

Behavior Of Real Gases: Deviation From Real Gas Behavior
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Liquefaction Of Gases

Liquefaction Of Gases
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The Liquid State

Vapor Pressure
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Surface Tension
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Viscosity
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Thermodynamics

Thermodynamic Terms

System And Surroundings
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Types Of System
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The State Of The System
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The Internal Energy as a State Function - Work
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The Internal Energy as a State Function - Heat
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The Internal Energy as a State Function - The General Case
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Applications

Work
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Isothermal and free expansion of an ideal gas
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Enthalpy, H A Useful New State function
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Extensive And Intensive Properties
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Heat Capacity
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The Relationship Between CP And CV Of An Ideal Gas
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Measurement Of ∆U And ∆H

Measurement Of ∆U And ∆H
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∆U Measurements
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∆H Measurements
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Enthalpy Change ∆H Of A Reaction - Reaction Enthalpy

Enthalpy Change ∆H Of A Reaction - Reaction Enthalpy
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Standard Enthalpy Of Reactions
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Enthalpy Changes During Phase Transformations
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Standard Enthalpy Of Formation
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Thermochemical Equations
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Hess's Law Of Constant Heat Summation
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Enthalpies Of Different Types Of Reactions

Standard Enthalpy Of Combustion
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Enthalpy Of Atomization
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Bond Enthalpy
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Enthalpy Of Solution
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Lattice Enthalpy
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Spontaneity

Enthalpy And Spontaneity
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Entropy And Spontaneity
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Gibbs Energy And Spontaneity
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Gibbs Energy Change And Equilibrium

Gibbs Energy Change And Equilibrium
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Equilibrium

Introduction

Introduction
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Equilibrium In Physical Processes

Solid - Liquid Equilibrium
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Liquid - Vapor Equilibrium
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Solid - Vapor Equilibrium
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Equilibrium Involving Dissolution Of Solid Or Gases In Liquids
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General Characteristics Of Equilibria Involving Physical Processes
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Equilibrium In Chemical Processes - Dynamic Equilibrium

Equilibrium In Chemical Processes - Dynamic Equilibrium
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Law Of Chemical Equilibrium And Equilibrium Constant

Law Of Chemical Equilibrium And Equilibrium Constant
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Homogenous Equilibria

Equilibrium Constant In Gaseous Systems
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Heterogeneous Equilibria

Heterogeneous Equilibria
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Applications Of Equilibrium Constants

Predicting The Extent Of A Reaction
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Predicting The Direction Of The Reaction
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Calculating Equilibrium Concentrations
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Relationship Between Equilibrium Constant K, Reaction Quotient Q, And Gibbs Energy G

Relationship Between Equilibrium Constant K, Reaction Quotient Q, And Gibbs Energy G
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Factors Affecting Equilibria

Effect Of Concentration Change
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Effect Of Pressure Change
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Effect Of Inert Gas Addition
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Effect Of Temperature Change
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Effect Of A Catalyst
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Ionic Equilibrium In Solution

Ionic Equilibrium In Solution
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Acids, Bases And Salts

Arrhenius Concept Of Acids And Bases
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The Bronsted - Lowry Concept Of Acids And Bases
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Lewis Acids And Bases
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Ionization Of Acids And Bases

Ionization Of Acids And Bases
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The Ionization Constant Of Water And Its Ionic Product
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The Ph Scale
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Ionization Constants Of Weak Acids
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Ionization Of Weak Base
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Relation Between KA And KB
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Di, Polybasic Acids & Di, Polyacidic Bases
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Factors Affecting Acid Strength
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Common Ion Effect In The Ionization Of Acids And Bases
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Hydrolysis Of Salts And The Ph Of Their Solutions
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Buffer Solutions

Buffer Solutions
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Solubility Equilibria Of Sparingly Soluble Salts

Solubility Equilibria Of Sparingly Soluble Salts
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Solubility Product Constant
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Common Ion Effect on Solubility Of Ionic Salts
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Redox Reactions

Classical Idea Of Redox Reactions - Oxidation Reduction Reactions

Classical Idea Of Redox Reactions - Oxidation Reduction Reactions
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Redox Reactions In Terms Of Electron Transfer Reactions

Introduction
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Competitive Electron Transfer Reactions
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Oxidation Number

Oxidation Number
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Combination Reactions
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Decomposition Reactions
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Displacement Reactions
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Disproportionation Reactions
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Balancing Of Redox Reactions
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Redox Reactions As The Basis For Titrations
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Limitations Of Concept Of Oxidation Number
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Redox Reactions And Electrode Processes

Redox Reactions And Electrode Processes
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Hydrogen

Position Of Hydrogen In The Periodic Table

Position Of Hydrogen In The Periodic Table
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Dihydrogen H2

Occurrence
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Isotopes Of Hydrogen
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Preparation Of Dihydrogen

Laboratory Preparation Of Dihydrogen
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Commercial Preparation Of Dihydrogen
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Properties Of Dihydrogen

Physical Properties
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Chemical Properties
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Uses Of Dihydrogen
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Hydrides

Ionic Or Saline Hydrides
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Covalent Or Molecular Hydride
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Metallic Or Non-Stoichiometric Hydrides
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Water

Physical Properties
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Structure Of Water
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Structure Of Ice
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Chemical Properties of Water
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Hard And Soft Water
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Temporary Hardness
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Permanent Hardness
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Hydrogen Peroxide

Hydrogen Peroxide: Preparation
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Hydrogen Peroxide: Physical Properties
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Structure
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Chemical Properties
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Storage
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Uses
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Heavy Water

Heavy Water
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Dihydrogen As A Fuel

Dihydrogen As A Fuel
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The S- Block Elements

Introduction

Introduction
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Group-1 Elements: The Alkali Metals

Electronic Configuration
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Atomic And Ionic Radii
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Ionization Enthalpy
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Hydration Enthalpy
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Physical Properties
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Chemical Properties
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Uses
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General Characteristics Of The Compounds Of Alkali Metals

Oxides And Hydroxides
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Halides
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Salts Of Oxo-Acids
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Anomalous Properties Of Lithium

Points Of Difference Between Lithium And Other Alkali Metals
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Points Of Similarities Between Lithium And Magnesium
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Some Important Compounds Of Sodium

Sodium Carbonate
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Sodium Chloride
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Sodium Hydroxide
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Sodium Hydrogen Carbonate
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Biological Importance Of Sodium And Potassium

Biological Importance Of Sodium And Potassium
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Group-2 Elements: Alkaline Earth Metals

Electronic Configuration
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Atomic And Ionic Radii
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Ionization Enthalpies
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Hydration Enthalpies
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Physical Properties
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Chemical Properties
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Uses
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General Characteristics Of The Compounds Of Alkaline Earth Metals

General Characteristics Of The Compounds Of Alkaline Earth Metals
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Anomalous Behavior Of Beryllium

Anomalous Behavior Of Beryllium
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Diagonal Relationship Between Beryllium And Aluminum
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Some Important Compounds Of Calcium

Calcium Oxide Or Quick Lime
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Calcium Hydroxide
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Calcium Carbonate
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Calcium Sulphate (Plaster Of Paris)
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Biological Importance Of Magnesium And Calcium

Biological Importance Of Magnesium And Calcium
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The P- Block Elements

Introduction

Introduction
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Group 13 Elements: The Boron Family

Electronic Configuration
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Atomic Radii
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Ionization Enthalpy
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Electronegativity
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Physical Properties
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Chemical Properties
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Important Trends And Anomalous Properties Of Boron

Important Trends And Anomalous Properties Of Boron
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Some Important Compounds Of Boron

Borax
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Orthoboric Acid
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Diborane
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Uses Of Boron And Aluminum And Their Compounds

Uses Of Boron And Aluminum And Their Compounds
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Group 14 Elements: The Carbon Family

Electronic Configuration
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Covalent Radius
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Ionization Enthalpy
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Electronegativity
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Physical Properties
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Chemical Properties
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Important Trends And Anomalous Properties Of Carbon

Important Trends And Anomalous Properties Of Carbon
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Allotropes Of Carbon

Diamond
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Graphite
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Fullerenes
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Uses Of Carbon
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Some Important Compounds Of Carbon And Silicon

Carbon Monoxide
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Carbon Dioxide
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Silicon Dioxide
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Silicones
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Silicates
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Zeolites
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Organic Chemistry - Some Basic Principles And Techniques

General Introduction

General Introduction
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Tetravalence Of Carbon: Shapes Of Organic Compounds

The Shape Of Carbon Compounds
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Some Characteristic Features Of ∏ Bonds
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Structural Representations Of Organic Compounds

Complete, Condensed And Bond-Line Structural Formulas
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Three Dimensional Representation Of Organic Compounds
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Classification Of Organic Compounds

Acyclic Or Open Chain Compounds
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Alicyclic Or Closed Chain Or Ring Compounds
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Nomenclature Of Organic Compounds

The Iupac System Of Nomenclature
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Iupac Nomenclature Of Alkanes
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Nomenclature Of Organic Compounds Having Functional Groups
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Nomenclature Of Substituted Benzene Compounds
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Isomerism

Structural Isomerism
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Stereoisomerism
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Fundamental Concepts In Organic Reaction Mechanism

Fission Of A Covalent Bond
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Nucleophiles And Electrophiles
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Electron Movements In Organic Reactions
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Electron Displacement Effects In Covalent Bonds
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Inductive Effect
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Resonance Structure
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Resonance Effect
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Electrometric Effect
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Hyperconjugation
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Types Of Organic Reactions And Mechanisms
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Methods Of Purification Of Organic Compounds

Sublimation
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Crystallization
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Distillation
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Differential Extraction
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Chromatography
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Qualitative Analysis Of Organic Compounds

Detection Of Carbon And Hydrogen
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Detection Of Nitrogen
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Detection Of Sulphur
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Test For Halogens
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Test For Phosphorus
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Quantitative Analysis

Carbon And Hydrogen
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Nitrogen
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Halogens
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Sulphur
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Phosphorus
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Oxygen
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Hydrocarbons

Classification

Classification
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Alkanes

Alkanes
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Nomenclature And Isomerism
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Preparation From Unsaturated Hydrocarbons
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Preparation From Alkyl Halides
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Preparation From Carboxylic Acids
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Physical Properties Of Alkanes
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Chemical Properties Of Alkanes
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Substitution Reactions
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Combustion
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Controlled Oxidation
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Isomerization
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Aromatization
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Reaction With Steam
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Pyrolysis
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Conformation-Sawhorse Projections
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Conformation-Newman Projections
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Alkenes

Structure Of Double Bond
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Nomenclature
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Isomerism
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Preparation From Alkynes
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Physical Properties
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Chemical Properties
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Alkynes

Nomenclature And Isomerism
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Structure Of Triple Bond
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Preparation From Calcium Carbide
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Preparation From Vicinal Dihalides
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Physical Properties
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Chemical Properties
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Acidic Character Of Alkyne
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Addition Reactions
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Polymerization
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Aromatic Hydrocarbon

Nomenclature And Isomerism
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Structure Of Benzene
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Aromaticity
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Preparation Of Benzene
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Physical Properties
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Electrophilic Substitution Reaction
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Nitration
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Halogenation
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Sulphonation
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Friedel-Crafts Alkylation Reaction
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Friedel-Crafts Acylation Reaction
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Mechanism Of Electrophilic Substitution Reaction
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Addition Reactions
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Directive Influence Of A Functional Group In Monosubstituted Benzene
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Carcinogenicity And Toxicity

Carcinogenicity And Toxicity
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Shape

Shape

Shape

Shape

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The Valence Shell Electron Pair Repulsion Theory

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