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Factors Affecting Equilibria
Chapter Name : Equilibrium
Sub Topic Code : 102_11_07_09_02
Topic Name : Factors Affecting Equilibria
Sub Topic Name : Effect Of Pressure Change
Introduction

• “A pressure change obtained by changing the volume can affect the yield of products in case of a gaseous reaction where the total number of moles of reactants and products are different. • In applying Le Chatelier’s principle to a heterogeneous equilibrium the effect of pressure changes on solids and liquids can be ignored because the volume (and concentration) of a solution/liquid is nearly independent of pressure.

Pre-Requisites:

Reaction, equilibrium constant, reaction quotient, gibbs energy

Key Words / FlashCards
Key Words Definitions (pref. in our own words)
Le Chatelier’s principle • Le Chatelier’s principle states that a “change in any of the factors that determine the equilibrium conditions of a system will cause the system to change in such a manner so as to restore the balance.” This is applicable to all physical and chemical equilibria.
Learning aids / Gadgets
Gadgets How it can be used
See saw • To obtain balance both sides should have equal weights.
Practical examples around us
Examples Explainations
What you learn in Theory:

• In applying Le Chatelier’s principle to a heterogeneous equilibrium the effect of pressure changes on solids and liquids can be ignored because the volume (and concentration) of a solution/liquid is nearly independent of pressure.

What you learn in Practice:

• In applying Le Chatelier’s principle to a heterogeneous equilibrium the effect of pressure changes on solids and liquids can be ignored because the volume (and concentration) of a solution/liquid is nearly independent of pressure.

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