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Group 14 Elements: The Carbon Family
Chapter Name : The P- Block Elements
Sub Topic Code : 102_11_11_06_03
Topic Name : Group 14 Elements: The Carbon Family
Sub Topic Name : Ionization Enthalpy
Introduction

• The first ionization enthalpy of group 14 members is higher than the corresponding members of group 13. • The influence of inner core electrons is visible here also. • In general the ionisation enthalpy decreases down the group. • Small decrease in ?iH from Si to Ge to Sn and slight increase in ?iH from Sn to Pb is the consequence of poor shielding effect of intervening d and f orbitals and increase in size of the atom.

Pre-Requisites:

Elements, periodic table, Group, ionization enthalpy

Activity:

• Group 14 has carbon, silicon which is found in the earth’s crust. • Carbon dating is done by using the C-14 isotope.

Real Life Question:

What is carbon used for?

Key Words / FlashCards
Key Words Definitions (pref. in our own words)
P block elements Have the last electron in the outermost p orbital.
Learning aids / Gadgets
Gadgets How it can be used
Glass, cement, coal Glass and cement have silicon in it, coal has carbon in it.
Real life uses :

• Carbon is found in every living tissue. • Silicon is used to make glass and cement.

Places to visit :

Chemistry lab, kitchen.

Practical examples around us
Examples Explainations
cement Cement has silicon in it.
What you learn in Theory:

• The first ionization enthalpy of group 14 members is higher than the corresponding members of group 13. • The influence of inner core electrons is visible here also. • In general the ionisation enthalpy decreases down the group. • Small decrease in ?iH from Si to Ge to Sn and slight increase in ?iH from Sn to Pb is the consequence of poor shielding effect of intervening d and f orbitals and increase in size of the atom.

What you learn in Practice:

• Group 14 has carbon, silicon which is found in the earth’s crust. • Carbon dating is done by using the C-14 isotope.

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